Iron-mediated AGET ATRP of styrene and methyl methacrylate using ascorbic acid sodium salt as reducing agent
نویسندگان
چکیده
منابع مشابه
Photocatalyzed iron-based ATRP of methyl methacrylate using 1,3-dimethyl-2-imidazolidinone as both solvent and ligand
Photochemistry serves as a wonderful means to facilitate various chemical reactions and is indeed unique in its powerful ability to meet the energetic requirements for conducting processes that would not be accomplished using thermal counterparts. In this work, a novel photocatalyzed Fe-based atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) was performed under UV irradia...
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Alcohols have been demonstrated to be efficient reducing agents for AGET-ATRP for the first time. Well-controlled polymerizations have been successfully achieved with the typical characteristics of "living"/controlled radical polymerization.
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Cellulose-graft-poly(methylmethacrylate) (cellulose-g-PMMA) copolymers were prepared by homogeneous atom transfer radical polymerization (ATRP) under mild conditions, in an attempt to develop an efficient way to modify the surface of cellulose. A cellulose macro-initiator was successfully synthesized by direct homogeneous acylation of cellulose with 2-bromopropionyl bromide in a room temperatur...
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The role of cobalt(II) complexes containing 2-formylpyrrolyl chelating ligands and phosphine ligands combined with a bromo-alkyl ester, an alkyl bromide or an azo compound in the formation of suitable initiator systems for vinyl monomer controlled radical polymerization was studied. The formation of syndiotactic-rich (Pr>0.7) poly(methyl methacrylate) (PMMA) and atactic (Pr=0.49) poly(styrene) ...
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High-level ab initio molecular orbital calculations are used to study the magnitude and origin of the penultimate unit effect in atom transfer radical polymerization (ATRP) of dimers involving the comonomers methyl acrylate (MA), methyl methacrylate (MMA), and propylene (P). The penultimate unit effects depend on the nature of the terminal unit and the halogen and can be significant, with the M...
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ژورنال
عنوان ژورنال: Chinese Journal of Polymer Science
سال: 2014
ISSN: 0256-7679,1439-6203
DOI: 10.1007/s10118-014-1481-2